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In a medium bowl, whisk together cornstarch, cocoa powder, 3 tablespoons of sugar, and salt until combined. Add 1/4 cup milk and whisk until smooth. Add egg and yolks and whisk until combined. Set aside.
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In a medium saucepan over moderate heat, bring to a boil the remaining 2 cups of milk and 3 tablespoons of sugar, stirring until sugar is dissolved. Remove from heat.
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Gradually pour the hot milk into the egg mixture, constantly whisking until smooth. Transfer mixture back into saucepan. Cook over medium-low heat, whisking constantly, until mixture thickens and coats the back of a spoon, 2-3 minutes. It should have a consistency similar to mayonnaise.
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Strain the pudding into a medium heatproof bowl. Add the chopped chocolate, butter, and vanilla and whisk until the chocolate and butter are completely melted and pudding is smooth. Transfer pudding to 4-ounce or 6-ounce ramekins and refrigerate for at least 3-4 hours until chilled. You can press a piece of plastic wrap directly onto the surface of the pudding to prevent it from creating a ‘skin’. Serve with lightly whipped cream if you like.
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Chocolate pudding can be covered with plastic wrap and refrigerated for up to 4 days. It does not freeze well.